33,755 research outputs found
Rapid Water Reduction to H_2 Catalyzed by a Cobalt Bis(iminopyridine) Complex
A cobalt bis(iminopyridine) complex is a highly active electrocatalyst for water reduction, with an estimated apparent second order rate constant k_(app) ≤ 10^7 M^(–1)s^(–1) over a range of buffer/salt concentrations. Scan rate dependence data are consistent with freely diffusing electroactive species over pH 4–9 at room temperature for each of two catalytic reduction events, one of which is believed to be ligand based. Faradaic H_2 yields up to 87 ± 10% measured in constant potential electrolyses (−1.4 V vs SCE) confirm high reactivity and high fidelity in a catalyst supported by the noninnocent bis(iminopyridine) ligand. A mechanism involving initial reduction of Co^(2+) and subsequent protonation is proposed
Space acceleration measurement system triaxial sensor head error budget
The objective of the Space Acceleration Measurement System (SAMS) is to measure and record the microgravity environment for a given experiment aboard the Space Shuttle. To accomplish this, SAMS uses remote triaxial sensor heads (TSH) that can be mounted directly on or near an experiment. The errors of the TSH are reduced by calibrating it before and after each flight. The associated error budget for the calibration procedure is discussed here
Fractal Markets Hypothesis and the Global Financial Crisis: Scaling, Investment Horizons and Liquidity
We investigate whether fractal markets hypothesis and its focus on liquidity
and invest- ment horizons give reasonable predictions about dynamics of the
financial markets during the turbulences such as the Global Financial Crisis of
late 2000s. Compared to the mainstream efficient markets hypothesis, fractal
markets hypothesis considers financial markets as com- plex systems consisting
of many heterogenous agents, which are distinguishable mainly with respect to
their investment horizon. In the paper, several novel measures of trading
activity at different investment horizons are introduced through scaling of
variance of the underlying processes. On the three most liquid US indices -
DJI, NASDAQ and S&P500 - we show that predictions of fractal markets hypothesis
actually fit the observed behavior quite well.Comment: 11 pages, 3 figure
Promoting independent learning skills using video on digital language laboratories
This is the author's PDF version of an article published in Computer assisted language learning ©2006. The definitive version is available at http://www.informaworld.com/The article discusses the potential for developing independent learning skills using the digital language laboratory with particular reference to exploiting the increasingly available resource of digital video. It investigates the potential for recording and editing video clips from online sources and digitalising clips from analogue recordings and reflects on the current status quo regarding the complex copyright regulations in this area. It describes two pilot self-access programmes based on video clips which were undertaken with University College Chester undergraduates and reflects on the value of the experience for students in developing a wide range of language skills as well as independent learning skills using their feedback on the experience
Generalized (m,k)-Zipf law for fractional Brownian motion-like time series with or without effect of an additional linear trend
We have translated fractional Brownian motion (FBM) signals into a text based
on two ''letters'', as if the signal fluctuations correspond to a constant
stepsize random walk. We have applied the Zipf method to extract the
exponent relating the word frequency and its rank on a log-log plot. We have
studied the variation of the Zipf exponent(s) giving the relationship between
the frequency of occurrence of words of length made of such two letters:
is varying as a power law in terms of . We have also searched how
the exponent of the Zipf law is influenced by a linear trend and the
resulting effect of its slope. We can distinguish finite size effects, and
results depending whether the starting FBM is persistent or not, i.e. depending
on the FBM Hurst exponent . It seems then numerically proven that the Zipf
exponent of a persistent signal is more influenced by the trend than that of an
antipersistent signal. It appears that the conjectured law
only holds near . We have also introduced considerations based on the
notion of a {\it time dependent Zipf law} along the signal.Comment: 24 pages, 12 figures; to appear in Int. J. Modern Phys
Photodetachment Cross Section of H- in Crossed Electric and Magnetic Fields. I. Closed-Orbit Theory
In this, the first of two papers, we obtain a simple analytic formula for the photodetachment cross section of H− in crossed electric and magnetic fields. The three-dimensional semiclassical approximation predicts oscillations in the spectrum and these oscillations are correlated with closed classical orbits. In the following paper [A. D. Peters and J. B. Delos, Phys. Rev. A 47, 3036 (1993)] we derive fully-quantum-mechanical formulas for the cross section in perpendicular electric and magnetic fields and show how these results can be reduced to the semiclassical results of this paper
Photodetachment Cross Section of H- in Crossed Electric and Magnetic Fields. II. Quantum Formulas and Their Reduction to the Result of the Closed-Orbit Theory
In this, the second of two papers, we derive general quantum formulas for the photodetachment cross section for H− in perpendicular electric and magnetic fields. The results are valid for any polarization and can be reduced to the semiclassical results of the first paper [A. D. Peters and J. B. Delos, Phys. Rev. A 47, 3020 (1993)]: a smooth background plus oscillatory terms. This connection between the quantum and semiclassical results is made using a stationary-phase approximation and it is shown that each stationary-phase point corresponds to a closed orbit
Harper operators, Fermi curves, and Picard-Fuchs equations
This paper is a continuation of the work on the spectral problem of Harper
operator using algebraic geometry. We continue to discuss the local monodromy
of algebraic Fermi curves based on Picard-Lefschetz formula. The density of
states over approximating components of Fermi curves satisfies a Picard-Fuchs
equation. By the property of Landen transformation, the density of states has a
Lambert series as the quarter period. A -expansion of the energy level can
be derived from a mirror map as in the B-model.Comment: v2, 13 pages, minor changes have been mad
Non-locality and Medium Effects in the Exclusive Photoproduction of Eta Mesons on Nuclei
A relativistic model for the quasifree exclusive photoproduction of
mesons on nuclei is extended to include both non-local and medium effects. The
reaction is assumed to proceed via the dominant contribution of the
S(1535) resonance. The complicated integrals resulting from the
non-locality are simplified using a modified version of a method given by
Cooper and Maxwell. The non-locality effects are found to affect the magnitude
of the cross section. Some possibilities reflecting the effects of the medium
on the propagation and properties of the intermediate S resonance are
studied. The effects of allowing the S to interact with the medium via
mean field scalar and vector potentials are considered. Both broadening of
width and reduction in mass of the resonance lead to a suppression of the
calculated cross sections.Comment: 19 pages, 7 figure
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